Ethanol Heptane Mix CDA 12-A 200 Proof - SDS
Safety Data Sheet (SDS)
According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations. Date of Issue: 04/22/2019.
Download Complete Ethanol Heptane Mix - Denatured Alcohol (CDA) 12-A Safety Data Sheet (SDS) here 
SECTION 1: IDENTIFICATION
1.1. Product Identifier
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Product Form: Mixture |
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Product Name: Ethanol Heptane Mix - Completely Denatured Alcohol (CDA) 12-A 200 Proof |
1.2. Intended Use of the Product No additional information available
1.3. Name, Address, and Telephone of the Responsible Party
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Company High Precision Gas LLC |
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1.4. Emergency Telephone Number
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Emergency Number |
: |
Professional Emergency Resource Services (PERS) |
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
GHS-US classification
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Flam. Liq. 2 |
H225 |
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Skin Irrit. 2 |
H319 |
| Carc. 1A | H350 |
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Repr. 1A |
H360 |
| STOT SE 3 | H336 |
| Aquatic Acute 1 | H400 |
| Aquatic Chronic 2 | H411 |
Full text of hazard classes and H-statement: See section 16
2.2. Label Elements
GHS-US Labeling
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Hazard Pictograms (GHS-US) |
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 GHS02 |
 GHS07 |
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Signal Word (GHS-US) |
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Danger |
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Hazard Statements (GHS-US) |
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H225 - Highly flammable liquid and vapour. H319 - Causes serious eye irritation. H336 - May cause drowsiness or dizziness. H350 - May cause cancer. H360 - May damage fertility or the unborn child. H400 - Very toxic to aquatic life. H411 - Toxic to aquatic life with long lasting effects. |
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Precautionary Statements (GHS-US) |
: |
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GHS08
2.3. Other Hazards
Exposure may aggravate pre-existing eye, skin, or respiratory conditions.
2.4. Unknown Acute Toxicity (GHS-US)
No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
Not applicable
3.2. Mixture
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Name |
Synonyms |
Product Identifier |
% |
GHS US classification |
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Ethyl alcohol |
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(CAS-No.) 64-17-5 |
95.2 |
Flam. Liq. 2, H225 Eye Irrit. 2A, H319 Carc. 1A, H350 Repr. 1A, H360 STOT SE 3, H336 |
| n-Heptane |
Heptane (n-) / Heptane / Normal heptane / Heptane, n- / HEPTANE |
(CAS-No.) 142-82-5 | 4.8 | Flam. Liq. 2, H225 Skin Irrit. 2, H315 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 |
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
4.1. Description of First-aid Measures
| First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). |
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First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty persists. |
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First-aid Measures After Skin Contact: Immediately drench affected area with water for at least 15 minutes. Immediately remove contaminated clothing. If exposed or concerned: Get medical advice/attention. |
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First-aid Measures After Eye Contact: Immediately rinse with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if irritation develops or persists. |
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First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain medical attention. |
4.2. Most Important Symptoms and Effects Both Acute and Delayed
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Symptoms/Injuries: May cause drowsiness and dizziness. May cause cancer. Causes serious eye irritation. May damage fertility. May damage the unborn child |
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Symptoms/Injuries After Inhalation: High concentrations may cause central nervous system depression such as dizziness, vomiting, numbness, drowsiness, headache, and similar narcotic symptoms. |
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Symptoms/Injuries After Skin Contact: Prolonged exposure may cause skin irritation. |
| Symptoms/Injuries After Eye Contact: Contact causes severe irritation with redness and swelling of the conjunctiva. |
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Symptoms/Injuries After Ingestion: Ingestion may cause adverse effects. |
| Chronic Symptoms: May cause cancer. May damage fertility or the unborn child. |
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand.
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
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Suitable Extinguishing Media: Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Water may be ineffective but water should be used to keep fire-exposed container cool. |
5.2. Special Hazards Arising From the Substance or Mixture
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Fire Hazard: Highly flammable liquid and vapor. |
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Explosion Hazard: May form flammable/explosive vapor-air mixture. |
| Reactivity: Reacts violently with strong oxidizers. Increased risk of fire or explosion. |
5.3. Advice for Firefighters
| Precautionary Measures Fire: Exercise caution with fighting any chemical fire. |
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Firefighting Instructions: Use water spray or fog for cooling exposed containers. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
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Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. |
| Hazardous Combustion Products: Carbon oxides (CO, CO2). |
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Other Information: Do not allow run-off from fire fighting to enter drains or water courses. |
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
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General Measures: Do not breathe vapor, mist or spray. Do not get in eyes, on skin, or on clothing. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking. Use special care to avoid static electric charges. |
6.1.1. For Non-Emergency Personnel:
| Protective Equipment: Use appropriate personal protective equipment (PPE). |
| Emergency Procedures: Evacuate unnecessary personnel. Stop leak if safe to do so. |
6.1.2. For Emergency Personnel:
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Protective Equipment: Equip cleanup crew with proper protection |
| Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Ventilate area. Eliminate ignition sources. |
6.2. Environmental Precautions
Prevent entry to sewers and public waters. Avoid release to the environment. Collect spillage.
6.3. Methods and Materials for Containment and Cleaning Up
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For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. As an immediate precautionary measure, isolate spill or leak area in all directions. |
| Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. Absorb and/or contain spill with inert material. Do not take up in combustible material such as: saw dust or cellulosic material. Use only non-sparking tools. |
6.4. Reference to Other Sections
See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
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Additional Hazards When Processed: Handle empty containers with care because residual vapors are flammable. |
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Precautions for Safe Handling: Avoid contact with skin, eyes and clothing. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist, spray, vapors. Take precautionary measures against static discharge. Use only non-sparking tools. |
| Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures |
7.2. Conditions for Safe Storage, Including Any Incompatibilities
| Technical Measures: Comply with applicable regulations. Take action to prevent static discharges. Ground and bond container and receiving equipment. Use explosion-proof electrical, ventilating, and lighting equipment. |
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Storage Conditions: Store in a dry, cool place. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Store locked up/in a secure area. Store in a well-ventilated place. Keep container tightly closed. Keep in fireproof place. |
7.3. Specific End Use(s) No additional information available
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), OSHA (PEL).
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n-Heptane (142-82-5) |
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USA ACGIH |
ACGIH TWA (ppm) |
400 ppm (Heptane, all isomers) |
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USA ACGIH |
ACGIH STEL (ppm) |
500 ppm (Heptane, all isomers) |
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USA NIOSH |
NIOSH REL (TWA) (mg/m³) |
350 mg/m³ |
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USA NIOSH |
NIOSH REL (TWA) (ppm) |
85 ppm |
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USA NIOSH |
NIOSH REL (ceiling) (mg/m³) |
1800 mg/m³ |
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USA NIOSH |
NIOSH REL (ceiling) (ppm) |
440 ppm |
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USA IDLH |
US IDLH (ppm) |
750 ppm |
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USA OSHA |
OSHA PEL (TWA) (mg/m³) |
2000 mg/m³ |
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USA OSHA |
OSHA PEL (TWA) (ppm) |
500 ppm |
8.2. Exposure Controls
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Appropriate Engineering Controls |
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Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. Gas detectors should be used when flammable gases or vapors may be released. Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof equipment. |
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Personal Protective Equipment |
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Gloves. Protective clothing. Protective goggles. Insufficient ventilation: wear respiratory protection.
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| Materials for Protective Clothing | : | Chemically resistant materials and fabrics. Wear fire/flame resistant/retardant clothing. |
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Eye and Face Protection |
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Chemical safety goggles. |
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Skin and Body Protection |
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Wear suitable protective clothing. |
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Respiratory Protection |
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If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. In case of inadequate ventilation, oxygen deficient atmosphere, or where exposure levels are not known wear approved respiratory protection. |
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Other Information |
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When using, do not eat, drink or smoke. |
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
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Physical State |
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Liquid |
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Appearance |
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No data available |
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Odor |
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No data available |
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Odor Threshold |
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No data available |
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pH |
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No data available |
| Evaporation Rate | : | No data available |
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Melting Point |
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No data available |
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Freezing Point |
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No data available |
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Boiling Point |
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No data available |
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Flash Point |
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No data available |
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Auto-ignition Temperature |
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No data available |
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Decomposition Temperature |
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No data available |
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Flammability (solid, gas) |
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Not applicable |
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Vapor Pressure |
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No data available |
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Relative Vapor Density at 20°C |
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No data available |
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Relative Density |
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No data available |
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Solubility |
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No data available |
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Partition Coefficient: N-Octanol/Water |
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No data available |
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Viscosity |
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No data available |
9.2. Other Information: No additional information available
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: Reacts violently with strong oxidizers. Increased risk of fire or explosion.
10.2. Chemical Stability: Extremely flammable liquid and vapor. May form flammable or explosive vapor-air mixture.
10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, heat, hot surfaces, sparks, open flames, incompatible materials, and other ignition sources.
10.5. Incompatible Materials: Strong acids, strong bases, strong oxidizers.
10.6. Hazardous Decomposition Products: Not expected to decompose under ambient conditions.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects
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Acute Toxicity: Not classified |
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n-Heptane (142-82-5) |
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LC50 Oral Rat |
> 5000 mg/kg |
| LD50 Dermal rabbit | 3000 mg/kg |
| LC50 Inhalation rat (ppm) | 103 g/m³ (Exposure time: 4 h) |
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ATE US (dermal) |
3000.000 mg/kg body weight |
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ATE US (Vapors) |
103.00 mg/I/4h |
| ATE (Dust/Mist) | 103.00 mg/I/4h |
Skin Corrosion/Irritation: Not classified.
Serious Eye Damage/Irritation: Causes serious eye irritation.
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Respiratory or Skin Sensitization: Not classified |
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Germ Cell Mutagenicity: Not classified |
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Carcinogenicity: May causes cancer. |
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Reproductive Toxicity: May damage fertility or the unborn child |
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Specific Target Organ Toxicity (Single Exposure): May cause drowsiness or dizziness. |
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Specific Target Organ Toxicity (Repeated Exposure): Not classified. |
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Aspiration Hazard: Not classified. |
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Symptoms/Injuries After Inhalation: High concentrations may cause central nervous system depression such as dizziness, vomiting, numbness, drowsiness, headache, and similar narcotic symptoms. |
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Symptoms/Injuries After Skin Contact: Prolonged exposure may cause skin irritation. |
| Symptoms/Injuries After Eye Contact: Contact causes severe irritation with redness and swelling of the conjunctiva. |
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Symptoms/Injuries After Ingestion: Ingestion may cause adverse effects. |
| Chronic symptoms: May cause cancer. May damage fertility or the unborn child. |
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
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Ecology - General |
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Very toxic to aquatic life. Toxic to life with long lasting effects. |
| n-Heptane (142-82-5) | ||
| LC50 fish 1 | 375 mg/l (Exposure time: 96 h - Species: Cichlid fish) | |
| EC50 Daphnia 1 | 0.1 mg/I |
12.2. Persistence and Degradability
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Completely Denatured Alcohol 12-A 200 Proof |
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Persistence and Degradability |
May cause long-term adverse effects in the environment. |
12.3. Bioaccumulative Potential
| Completely Denatured Alcohol 12-A 200 Proof | |
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Bioaccumulative Potential |
Not established. |
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n-Heptane (142-82-5) |
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Log Pow |
4.66 |
12.4. Mobility in Soil No additional information available
12.5. Other Adverse Effects
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Other Information |
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Avoid release to the environment. |
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste Treatment Methods
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Waste Disposal Recommendations: Dispose of contents/container in accordance with local, regional, national, and international regulations. |
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Additional Information: Handle empty containers with care because residual vapors are flammable. |
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Ecology - Waste Materials: Avoid release to the environment. This material is hazardous to the aquatic environment. Keep out of sewers and waterways. |
SECTION 14: TRANSPORT INFORMATION
The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored, and can vary based on a number of variables that may or may not have been known at the time the SDS was issued.
14.1 In Accordance with DOT
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Transport document description |
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ETHYL ALCOHOL SOLUTIONS (Ethyl alcohol, heptane) |
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Hazard Class |
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3 |
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Identification Number |
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UN1170 |
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| Label Codes |
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3 |
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| Packing Group | : | II | |
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Marine Pollutant |
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Marine pollutant |
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| ERG Number | : | 127 | |
14.2 In Accordance with IMDG
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Proper Shipping Name |
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ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTIONS) |
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Hazard Class |
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3 |
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Identification Number |
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UN1170 |
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| Packing Group |
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II |
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Label Codes |
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3 |
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EmS-No. (Fire) |
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F-E |
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EmS-No (Spillage) |
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S-D |
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Marine Pollutant |
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Marine pollutant |
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14.3 In Accordance with IATA
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Proper Shipping Name |
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ETHYL ALCOHOL SOLUTION |
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Packing Group |
: |
II |
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Identification Number |
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UN1170 |
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| Hazard Class |
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3 |
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| Label Codes | : | 3 | |
| ERG Code (IATA) | : | 3L | |
SECTION 15: REGULATORY INFORMATION
15.1. US Federal Regulations
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Completely Denatured Alcohol 12-A 200 Proof
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SARA Section 311/312 Hazard Classes |
Health hazard - Specific target organ toxicity (single or repeated exposure) |
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n-Heptane (142-82-5) |
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Listed on the United States TSCA (Toxic Substances Control Act) Inventory |
15.2. US State regulations
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n-Heptane (142-82-5) |
| U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List |
SECTION 16: OTHER INFORMATION
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Date of Latest Revision |
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04/22/2019 |
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Other Information |
: |
This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 |
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GHS Full Text Phrases: |
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Aquatic Acute 1 |
Hazardous to the aquatic environment - Acute Hazard Category 1 |
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Aquatic Chronic 1 |
Hazardous to the aquatic environment - Chronic Hazard Category 1 |
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Aquatic Chronic 2 |
Hazardous to the aquatic environment - Chronic Hazard Category 2 |
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Asp. Tox. 1 |
Aspiration hazard Category 1 |
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Carc. 1A |
Carcinogenicity Category 1A |
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Eye Irrit. 2 |
Serious eye damage/eye irritation Category 2 |
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Eye Irrit. 2A |
Serious eye damage/eye irritation Category 2A |
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Flam. Liq. 2 |
Flammable liquids Category 2 |
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Repr. 1A |
Reproductive toxicity Category 1A |
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Skin Irrit. 2 |
Skin corrosion/irritation Category 2 |
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STOT SE 3 |
Specific target organ toxicity (single exposure) Category 3 |
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H225 |
Highly flammable liquid and vapour |
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H304 |
May be fatal if swallowed and enters airways |
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H315 |
Causes skin irritation |
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H319 |
Causes serious eye irritation |
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H336 |
May cause drowsiness or dizziness |
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H350 |
May cause cancer |
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H360 |
May damage fertility or the unborn child |
|
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H400 |
Very toxic to aquatic life |
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H410 |
Very toxic to aquatic life with long lasting effects |
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H411 |
Toxic to aquatic life with long lasting effects |
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
SDS US (GHS HazCom)